Really depends on your set up. Assuming this is not a broody with chicks but chicks you're raising, I wouldn't let them out earlier than 1 week or so, because they're harder to catch when they're super young, plus I have adult hens wandering around.
My current group of chicks had "mini run" access from 10 days old (so an enclosure of about 12 sq ft) and full run access at 15 days.