Be sure to give them some acclimation time, especially at only 3 weeks old. You may want to take them off the heat for a few days before you put them out. And be prepared for a first class chicky temper tantrum the first night. They don't like change, and suddenly moving to the big, scary outdoors is a huge change. They'll likely huddle - this is as much for security as it is for warmth. With chicks (and chickens) there is no courtesy....it's every bird for him/herself! There's safety in numbers, and they know that the chick on the outside of the pile is the most likely to be picked off, so none of them wants to be on the outside! "No, no...take her...she poops in the food pan!" And the first time in the dark is an added reason to throw a temper tantrum, hoping you will melt and bring them back in. If you know your setup is as predator proof as humanly possible, and they are just yelling at you because they're scared of the dark, pour yourself a margarita. In fact, I've found over the years that Margarita Mix is the most important part of my chicken first aid kit!
If your temps are much lower than the 50s, do yourself and them a favor and harden yourself to wait another week or so. Better safe than sorry. Remember that my chicks start out there from the get-go, and have Mama Heating Pad as a heat source for the first three weeks. They spend more time outside of it than under it, so they are acclimating themselves to ambient temperatures from the start. They self-regulate. In your case you've been doing the regulating for them. So give them some time to adapt a bit before you put them out. Good luck!
If your temps are much lower than the 50s, do yourself and them a favor and harden yourself to wait another week or so. Better safe than sorry. Remember that my chicks start out there from the get-go, and have Mama Heating Pad as a heat source for the first three weeks. They spend more time outside of it than under it, so they are acclimating themselves to ambient temperatures from the start. They self-regulate. In your case you've been doing the regulating for them. So give them some time to adapt a bit before you put them out. Good luck!