i caught 2 skunks when i was trying to catch my neighbors cat. Neighbors cat would come crap on my deck every morning.. would irritate the hell out of me.. I wanted to shoot it but my wife wouldnt let me.. So I borrowed a havahart trap from my buddys hardware store and set a can of tuna in it.. next morning when i woke up.. Skunk.. I threw a blanket over it and it didnt spray until I put it in the bed of the truck.. then it sprayed. took it to the local park about 5 miles away and let it go..
Left the trap on the back deck for a while.. It did smell for about a week but the cat stayed away..
2 weeks later it started up again.. set up the trap... bang.. another GD skunk.. This one had sprayed itself silly all night.. Same routine.. Covered it with the same blanket and drove it to a different park and let it go.
I finally did get the cat.. Gave the neighbor 3 options.. keep it inside, get rid of it, or id take matters in my own hands..
Cat never bothered me again.