White "gel" stuck on to my chicken's butt? Please help! Emergency!

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No. It just confirms she has an oviduct obstruction.

What occurs in such an obstruction is the ceca get blocked. The ceca is where the cecal poop originates, but the ceca also distribute fluids to the tissues of the body. During obstruction, these fluids are flushed down and out of the reproductive tract. That's why the awful odor.

But the consequences for the hen are risks of dehydration. It's a vicious circle, making it more difficult to resolve the obstruction. This is why pushing fluids is very crucial.
 
If you have a qualified avian vet available to do the surgery, then yes, it's an option. The surgery is not without risk, though.

Continue the calcium once a day, the antibiotic two hours later and push the fluids.
 

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