I've seen that exact behavior before. I had a cockerel with a flock that had no mature rooster, some mature hens, and some pullets his age. As he matured the pullets and most of the other hens would accept him and willingly mate with him, but the dominant hen would knock him off when he tried to mate another one in her sight. I've done that a few times, the transition from her being flock master to him taking over was always pretty peaceful, but not this time.
Eventually he matured enough that he decided to become flock master instead of letting her have the position. For two days it was pretty brutal. He was bigger than her and wasn't running away anymore so she became the one picked on. He kept her away from the rest of the flock. He would chase her away and if he got close enough he'd peck her, usually trying for the head. She never became bloodied but it could have easily happened.
After two days they reached an accommodation. She was still the dominant hen but he was now the flock master. She stopped bullying him, he stopped attacking her. They became best buddies. The flock was again peaceful.
I don't know what will happen with yours if you let them fight it out. I had the advantage of the hen having a lot of room to run away and get away. In tight quarters it could have been a different story. Each chicken has it's own personality so you can't tell what the outcome will be. I decided since no blood was drawn I'd give them a chance to work it out and they did. You've had blood drawn.
The options I see for you are to let them fight it out, get rid of one of them (I hold my hens as responsible for flock peace as the males), or pen him separately for a while to see if he can mature enough the hen will just accept him instead of trying to bully him to hold onto her flock master position.
Good luck!