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I would wait a few weeks and take a new picture. Your chicks are too young to sex. There are a few breeds you can tell the sex at one day old (sex links, Welsummers..), and a few you can tell at a few weeks old...especially if the rooster is a different color than the hen (the feathers come in darker). Buff Orpingtons can be difficult to sex, I can attest to that...but it still takes weeks to see comb development, etc. Also, I took the advice to not introduce "treats" until after their first week or two of life. Not sure what others on BYC do.