I steamed two dozen eggs yesterday and they peeled like a dream. Got the water boiling, set the eggs in the steamer basket, steamed 12 minutes, and dunked them in cold water. Shook in a glass with a little water and the peels slipped right off. These were fresh eggs, too- between one and 6 days old.
Yes, works really well. I think mine took 20min. because I put the eggs in the steamer before the water was boiling. A couple of the eggs were actually not quite completely "Hard Boiled"