Hi there, welcome to BYC!
Sometimes that can be a new layer hiccup. What is the age of your ladies? Where are you finding these shell less eggs?
It is unlikely a calcium issue as far as intake goes according to your description of feed stuffs. Go easy on the afternoon corn as it's low nutrient high energy treat and can diminish protein and amino acids too far if given in excess.
Sounds more like the system is trying to work itself out. If the gal has been laying for a while and it continues and she is not a new layer then she may have a defective shell gland or other reproductive defect going on.
Pay attention to that gal for any signs of egg binding. Although most softees will be expelled in the same manner as poo... sometimes a shell-less egg will not give enough resistance to be able to pushed through... getting stuck inside. Sometimes egg binding can be cause by too large of eggs also, but softees should be watched. When folks give bound hens a quick calcium supplement like tums it is to support the muscle contractions and not to strengthen the shell... though it has been used for some defective hens to strengthen shells long term.
Warm Epsom salt baths also absorb magnesium through the skin to support muscles and relax the hen.. when binding is an issue.
Please note.. Sussex, being dual purpose hens and not light bodies layers will do *best* on at least 18% protein. If you have a grower, all flock, or other options.. consider using it with a calcium source on the side free choice. The higher amino acid levels really seem to make a difference... Here in the US most layer feed has 16% protein which is the bare minimum to keep a light bodied bird in good condition. Since making the switch (to flock raiser with 20% protein) my birds enter molt less harshly and return to lay sooner... It's great that you're able to free range.. that helps balance things out.