If you have a fan in your incubator, the 99.5 is correct. If it's still-air it needs to be higher (and someone else will have to fill you in on the details). Humidity will vary depending on your altitude and ambient humidity. In winter, most people need to run the humidity higher to compensate for lower external humidity. For first-timers, I recommend using the directions that come with your incubator and taking careful notes. In particular, measure the size of the air cells at each candling by drawing a circle around them. By hatch-time, you want those air cells to take up between 1/4 and 1/3 of the total volume of the egg. Any less and babies will drown, more and they won't develop properly. If you're monitoring it, you can adjust humidity and other factors to compensate from air cells growing too fast or slow. Also, your records will allow you to adjust for next time.
In other respects, hatching is much like with chicken eggs except it takes 28 days for mallard-derivatives (most domestic breeds) and 35 days for muscovies.
Good luck!