How do you plan to deal with chicks that you've managed to identify as cockerels? I've found that I lack the sturdy resolve to cull out a male chick once I've discovered I have one. I now have a three-month old "spare" roo in the lineup.
The way I ascertain the pullets from the cockerels is to watch the comb color as the chicks approach age three and four weeks of age. This has never let me down. The pullets will maintain a washed out pink hue on their very inconspicuous combs, while a cockerel will show a definite yellowing of a comb that is showing signs of developing.
By age six weeks, the comb on a cockerel is trending a very obvious red-orange when compared to the pullets, whose combs are still barely recognizable and still remain a very pale pink.