I did the ant test that @dawg53 had suggested in an earlier post. I put DE on the pile and came back the next day and there were still ants. I put some permethrin dust on the ant pile and the next day no ants. They either moved or died.
I actually did try DE on ants (like you, I bought a bag (small) of it when I first got chickens, because I thought it was a great idea... and then I didn't know what to do with it). Had a colony of ants in my wood chip pile, dumped the entire amount of DE on it and the ants did disappear.
Of course they could've just moved somewhere else in the yard, but at least they vacated the wood chips. Or maybe it's the sheer amount of DE I dumped that basically suffocated them, who knows.