She does look a little on the chubby side what all do you feed?
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Looks good. I don't think some extra dog food or cat food is going to cause your duck to get over weight just start small and see if it helps with feathers etc. Your both look very healthy and in good feathers.
Well she is enjoy her snack right? Her feathers do look like they need some help.
She did have a molt already?
Okay well this maybe just Martha I guess when she molts again that should tell you if this is going to be an on going issue with her. As long as she is eating drinking and staying involved with the flock, clear eyed etc I'd just keep an eye on her and wait. Not a lot else you can do.
Did you try dog kibble yet?