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There is REAL deep litter and there is "deep bedding". Deep litter, as mentioned, is a compost pile that breaks down if managed properly and that includes keeping it with the proper amount of moisture and materials. Deep bedding is just something like pine shavings only several inches deep. It doesn't really break down but will dry out the poop. If these people's coops stunk there are some possibilities:
1) too many chickens for the square footage of bedding. It can only deal with so much. I rake the poop and shavings in my coop every morning.
2) not enough ventilation - the best way to kill your chickens in the winter in cold climates or in the summer in hot climates.
3) they weren't using true deep litter.
Temperature question. How warm is too warm in my coop? 5 1ish week old chicks and 2 2ish week old ducklings? With the heat lamp on it approaches 100 deg in the coop during the day. Without the heat lamp it stays about 80-85. What temp should I be trying to keep it around?
100 is too hot for any of those birds. If you are doing the heat lamp thing, the "usual" temperature starts at 90-95F the first week, dropping 5F each week until they are fully feathered at 4 weeks. At that point they need no supplemental heat. Thus at 80-85F ambient, you really shouldn't need to heat more than a couple of weeks. But let the birds tell you. They will go under the heat if they are cold and stay away from it otherwise. The food and water should be as far from the heat as possible so they don't have to be in the heat when they don't want to be.